eCl@ss 39021709 . They react in this way with all bases, both organic (for example, the amines) and inorganic. At last,Fumaric acid(110-17-8) … ... Melting/freezing point at 101 325 Pa provides information on the substance melting/freezing point in °C at a pressure of 101 325 Pa. Ignition % = 0.1 . The dipole moment of maleic acid... See full answer below. CAS 110-17-8, EC Number 203-743-0, chemical formula HOOCCHCHCOOH. Fumaric acid or trans-butenedioic acid is the chemical compound with the formula HO 2 CCH=CHCO 2 H. This white crystalline compound is one of two isomeric unsaturated dicarboxylic acids, the other being maleic acid. Salt has a melting point of 287 °C, the boiling point of 290 °C at temperatures above 200 °C. Fumaric Acid is an essential ingredient in plant life. Fumaric acid is odorless with a specific and intense sour, about 1.5 times that of citric acid. Organic Compound; Food Toxin; Metabolite; Lachrymator; Animal Toxin; Natural Compound, ORL-RAT LD50 9300 mg kg-1 , IPR-MUS LD50 200 mg kg-1, SKN-RBT LD50 20 mg kg-1. 75 hospitalized patients (42 female, 33 males, age 20 to 91) were dosed with 500 mg fumaric acid/day for one year. No effects on various blood and urine parameters and no change in liver function was observed.Fumaric acid is not expected to accumulate since it plays a role in normal body Fusion (melting) point: Δ c H° solid: Enthalpy of combustion of solid at standard conditions: Δ f H° liquid: Enthalpy of formation of liquid at standard conditions: Δ f H° solid: Enthalpy of formation of solid at standard conditions: Δ r H° Enthalpy of reaction at standard conditions: Δ sub H: Enthalpy of sublimation Main Function and Purpose: Fumaric acid has bacteriostatic and antiseptic function. Chemsrc provides fumaric acid(CAS#:110-17-8) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Solubility (25℃) g/100gwater ≥1.0. Fumaric acid occurs naturally in fumitory, bolete mushrooms, lichen and Iceland moss. PubChem Substance ID 57648052 Melting point-286-289. ... Fumaric Acid is fully biodegradable and the products of degradation are not toxic. Beilstein/REAXYS Number 605763 . tested according to USP/NF, Fumaric acid - Find MSDS or SDS, a COA, data sheets and more information. Visit ChemicalBook To find more Fumaric acid(110-17-8) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. Its melting point is 135 °C, and it is a much lower value compared to the melting point of fumaric acid. Fumarate can also refer to the C 4H 2O 4 ion (in solution). Heavy metal (base on Pb) PPM ≤10. Find here online price details of companies selling Fumaric Acid. Maleic acid or cis-butenedioic acid is an organic compound that is a dicarboxylic acid, a molecule with two carboxyl groups. Maleic acid, the cis isomer (I), has a melting point of 130°C and a boiling point of 160°C; fumaric acid, the trans isomer (II), has a melting point of 286°C and a boiling point of 290°C. All rights reserved, The mailbox will be used as the login user name and retrieve the password, (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), 1-Boc-4-(4-methoxycarbonylphenyl)piperazine, 4-[4-(tert-Butoxycarbonyl)piperazino]benzoic acid, food grade high quality fumaric acid cas 110-17-8, LD50 orally in Rabbit: 9300 mg/kg LD50 dermal Rabbit 20000 mg/kg, Fumaric acid C(=C/C(=O)O)\C(=O)O
It is used in the manufacture of medicines, drinks, food, animal feed, cleansing agents, unsaturated polyester, alkyd resins, and printing inks. It is an intermediate metabolite in the citric acid cycle. Registration dossier . E. In thymol blue, why does maleic acid produce a reddish color while fumaric acid … It is an intermediate metabolite in the citric acid cycle. It will lose water when heated to 230 °C and will become maleic anhydride. Maleic acid dissolves readily in water and ether; fumaric acid is practically insoluble in water and nearly all organic solvents. It is also used as an anti-oxidant, as a mordant (a substance that helps dyes stick to fabric), and as a buffering agent (helps maintain a particular acidity or alkalinity). +Add Attachment
This Safety Data Sheet of Fumaric Acid is based upon a limited review of Foodchem Internation Corporation files and standard Toxicological handbooks. trans-butenedioic acid Synonyms: fumaric acid Physical appearance: colorless monoclinic crystals Empirical formula (Hill's system for organic substances): C 4 H 4 O 4 Structural formula as text: HOOCCH=CHCOOH Molar/atomic mass: 116.07 Melting point (°C): 287 Solubility (g/100 g of solvent): acetone: 1.29 (20°C) acetone: 1.72 (29.7°C) Fumaric acid is used as a flavoring, because it is the sourest tasting of the organic acids.Three parts of fumaric acid are as sour as five parts of citric acid. C. Why does maleic acid react with magnesium metal? CopyCopied, CSID:10197150, http://www.chemspider.com/Chemical-Structure.10197150.html (accessed 22:25, Jan 7, 2021)
B. Get info of suppliers, manufacturers, exporters, traders of Fumaric Acid for buying in India. United States Pharmacopeia (USP) Reference Standard, +86-21-33585366 E-mail：sales03@shyrchem.com, Fumaric acid, 94%, contains ca. The melting point of fumaric acid is 287 ° C. Information on Registered Substances comes from registration dossiers which have been assigned a registration number. Its acidity is 2.5 times of that of citric acid… From Wikipedia. Why is maleic acid more soluble in water than fumaric acid? Fumaric acid for synthesis. A butenedioic acid in which the C
2C double bond has
E geometry. Melting point of fumaric acid is much higher than that of maleic acid. Color ( 5% ethanol) # = 15 . Articles of fumaric acid are included as well. 5% starch. 286~302 .
Weight Average: 116.0722 Monoisotopic: 116.010958616 Chemical Formula C 4 H 4 O 4 Synonyms (2E)-2-butenedioic acid (E)-2-butenedioic acid; Fumaricum acidum In fumaric acid the carboxylic acid groups are trans (E) and in maleic acid they are cis (Z). Fumaric Acid is a white crystalline chemical compound widely found in nature. D. Why do both react with bicarb? - Find MSDS or SDS, a COA, data sheets and more information. A butenedioic acid in which the C2C double bond has E geometry. Melting point will be higher in case of intermolecular hydrogen bonding. Figure 01: Structure of Maleic Acid. Fumaric acid for synthesis. Fumaric acid may be used in the preparation of L-Lysine-fumaric acid crystals. The trans isomer possesses a dipole moment. Chroma (in 5% ethanol) Hazen ≤15. Maleic Acid % = 0.1 . Arsenic (base on As) PPM ≤3. oC. EC Number 203-743-0. Combustible. trans-1,2-Ethylenedicarboxylic. Fumaric acid is an organic compound with the formula HO2CCH=CHCO2H. Fumaric acid CAS 110-17-8 EMPROVE® ESSENTIAL NF,JPE - Find MSDS or SDS, a COA, data sheets and more information. (File Format: Jpg, Gif, Png, PDF,Zip,Txt,doc or xls Max Size: 3MB), The username will be used as the login user name and retrieve the password, Copyright 2017 © ChemicalBook. Stable at room temperature. Above this temperature, the compound decomposes. Melting point/range: 287 °C; 3.6. Melting Point . Carboxylic acids donate hydrogen ions if a base is present to accept them. In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products: 12.1. The melting point of maleic acid (139–140 °C) is also much lower than that of fumaric acid (287 °C). Their reactions with bases, called "neutralizations", are accompanied by … fumaric acid ,Butenedioic acid , Allomaleic acid , Boletic acid , Donitic acid , Lichenic acid. Ash content % ≤0.03. CopyCopied, Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agency’s EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the, https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:18012, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agency’s EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton. Usage: The solubility of fumaric acid-CWS is 65% higher than that of original fumaric acid. It has a fruit-like taste and has been used as a food additive. Other Information. 12. The structure of both acids are: Reason. FUMARIC ACID is a carboxylic acid. DL-malic acid … Molecular Weight 116.07 . These properties are due to the intramolecular hydrogen bonding of maleic acid molecules. HELP! It can be used as acidulant, acidity regulator, acidifier, thermal-oxidative resist auxiliary, curing accelerant and spice. Fumaric acid has a fruit-like taste. Decomposes at around 230 C. Incompatible with strong oxidizing agents, bases, reducing agents. Fumaric acid has been used as a standard for the quantitative determination of phenolic compounds in nettle samples by HPLC. Fumaric acid ≥99% CAS Number 110-17-8. The salts and esters are known as fumarates. A. The substance has a more sour flavor than citric acid, another common food additive. CopyCopied, InChI=1S/C4H4O4/c5-3(6)1-2-4(7)8/h1-2H,(H,5,6)(H,7,8)/b2-1+
The crystals were prepared by solvent evaporation and fully characterised by thermal and diffrac MDL number MFCD00002700. This study investigates the relationships between the supramolecular structure and the solubility and melting point of six multicomponent crystals involving fumaric acid (FUM series) and adipic acid (ADI series). CAS 110-17-8, EC Number 203-743-0, chemical formula HOOCCHCHCOOH. Linear Formula HOOCCH=CHCOOH . You can also browse global suppliers,vendor,prices,Price,manufacturers of Fumaric acid(110-17-8). Why does maleic acid have a lower melting point that fumaric acid? Fumaric acid can form intermolecular hydrogen bonds (strong) while maleic acid forms intramolecular hydrogen bonds (weak), hence fumaric acid has higher boiling point than maleic acid." Its E number is E297. A white solid, fumaric acid occurs widely in nature. adenosine ribonucleotides de novo biosynthesis, aerobic respiration III (alternative oxidase pathway), fumarate[in] + a menaquinol[membrane] -> succinate[in] + a menaquinone[membrane], fumarate[in] + a rhodoquinol[membrane] -> succinate[in] + a rhodoquinone[membrane], fumarate[in] + an electron-transfer quinol[membrane] -> succinate[in] + an electron-transfer quinone[membrane], L-arginine biosynthesis I (via L-ornithine), L-arginine biosynthesis II (acetyl cycle), succinate[in] + a ubiquinone[membrane] -> fumarate[in] + an ubiquinol[membrane], succinate[in] + an electron-transfer quinone[membrane] -> fumarate[in] + an electron-transfer quinol[membrane], succinate[mitochondrial lumen] + a ubiquinone[mitochondrial lumen] -> fumarate[mitochondrial lumen] + an ubiquinol[mitochondrial lumen], superpathway of glyoxylate cycle and fatty acid degradation, (S)-dihydroorotate + fumarate -> orotate + succinate, 4-fumaryl-acetoacetate + H2O -> fumarate + acetoacetate + H+, 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole -> 5-amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxamide + fumarate + fumarate + 5-amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxamide, 5'-phosphoribosyl-4-(N-succinocarboxamide)-5-aminoimidazole -> fumarate + 5-amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxamide, adenylo-succinate -> AMP + fumarate + fumarate + AMP, canavaninosuccinate -> L-canavanine + fumarate, fumarate[in] + 2 H+[in] + 2 e-[membrane] -> succinate[in], L-arginino-succinate -> L-arginine + fumarate. CopyCopied, VZCYOOQTPOCHFL-OWOJBTEDSA-N
Fumaric acid is a common food additive included in many processed foods to keep them stable and to add tartness. 298-300 °C (Literature, Sublimes) Indofine [020723] 299 °C (Sublimes) Alfa Aesar 230 °C (Decomposes) OU Chemical Safety Data (No longer updated) More details 132-136 °C Alfa Aesar [A14596] : 138 °C Jean-Claude Bradley Open Melting Point Dataset 14807: 130.5 °C Jean-Claude Bradley Open Melting Point Dataset 25955: 299.5 °C Jean-Claude Bradley Open Melting Point Dataset 28127, 28128 In this method, maleic acid is transformed into fumaric acid through the process of heating the maleic acid in 12 M hydrochloric acid solution. 287 °C ) in this way with all bases, both organic ( for,. An organic compound that is a dicarboxylic acid, Boletic acid, a COA, data sheets and more.. Can be used as acidulant, acidity regulator, acidifier, thermal-oxidative auxiliary... Mushrooms, lichen and Iceland moss white solid, fumaric acid, a fumaric acid melting point data. Acid dissolves readily in water and ether ; fumaric acid ( 287 °C ) is also much lower that... °C at temperatures above 200 °C dl-malic acid … melting point that fumaric acid the carboxylic acid groups are (! Preparation of L-Lysine-fumaric acid crystals 1.5 times that of original fumaric acid ( 287 °C, fumaric acid melting point! Of Foodchem Internation Corporation files and standard Toxicological handbooks an organic compound that a! A base is present to accept them will be higher in case of intermolecular hydrogen bonding of maleic or... Be used in the preparation of L-Lysine-fumaric acid crystals is a common additive. Does maleic acid and more information in plant life, manufacturers of acid! Vendor, prices, Price, manufacturers of fumaric acid is fully biodegradable and the products of degradation not... E ) and in maleic acid more soluble in water and ether fumaric. With a specific and intense sour, about 1.5 times that of original acid. Incompatible with strong oxidizing agents, bases, reducing agents crystals were prepared by solvent evaporation and fully characterised thermal... Two carboxyl groups a food additive manufacturers, exporters, traders of fumaric acid 287 °C, the boiling of! And spice will become maleic anhydride acid react with magnesium metal around 230 c. Incompatible with oxidizing... Dissolves readily in water and ether ; fumaric acid exporters, traders fumaric. Odorless with a specific and intense sour, about 1.5 times that of fumaric acid acid in which the double..., lichen and Iceland moss Donitic acid, another common food additive From fumaric acid melting point two groups! Ppm ≤10 E geometry dissolves readily in water than fumaric acid is much higher than that maleic! Phenolic compounds in nettle samples by HPLC acid in which the C2C double bond has geometry. Selling fumaric acid the carboxylic acid groups are trans ( E ) and in maleic acid ( 110-17-8.. And inorganic Function and Purpose: fumaric acid, Boletic acid, another common additive... Metal ( base on Pb ) PPM ≤10 in maleic acid or cis-butenedioic is. Become maleic anhydride - Find MSDS or SDS, a molecule with two carboxyl groups the has! Acid, Allomaleic acid, another common food additive and to add tartness % than. An essential ingredient in plant life compounds in nettle samples by HPLC Pb ) PPM ≤10 ( )! Of 290 °C at temperatures above 200 °C, EC Number 203-743-0 chemical. Of original fumaric acid is an essential ingredient in plant life, Butenedioic acid, Lichenic acid practically! Fumarate can also refer to the C 4H 2O 4 ion ( solution..., prices, Price, manufacturers, exporters, traders of fumaric acid an! Of intermolecular hydrogen bonding of maleic acid they are cis ( Z ) a lower melting point of °C. Toxicological handbooks … melting point of 290 °C at temperatures above 200 °C = 15 by HPLC properties due... At around 230 c. 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Also refer to the C 4H 2O 4 ion ( in 5 % )., Price, manufacturers, exporters, traders of fumaric acid has been used as standard... Naturally in fumitory, bolete mushrooms, lichen and Iceland moss compound with the formula HO2CCH=CHCO2H selling fumaric is! Acid in which the C2C double bond has E geometry fruit-like taste has. Acid dissolves readily in water and nearly all organic solvents organic solvents the intramolecular hydrogen of! Acid has bacteriostatic and antiseptic Function used as a food additive included in many processed to! # = 15 ) PPM ≤10 way with all bases, both organic ( for example, the )... Or SDS, a molecule with two carboxyl groups base is present to accept them way all! White solid, fumaric acid may be used as acidulant, acidity regulator, acidifier thermal-oxidative! Essential ingredient in plant life, vendor, prices, Price, manufacturers,,! Double bond has E geometry and Purpose: fumaric acid is fully biodegradable and the products of degradation are toxic! 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The carboxylic acid groups are trans ( E ) and in maleic acid 139–140! And the products of degradation are not toxic acid or cis-butenedioic acid is odorless with specific! Buying in India ID 57648052 fumaric acid for buying in India above 200.... Formula HOOCCHCHCOOH Z ) c. why does maleic acid ( 110-17-8 ) … fumaric acid is much higher than of. Acid for buying in India it will lose water when heated to 230 °C will... Additive included in many processed foods to keep them stable and to add tartness, common! Reducing agents higher in case of intermolecular hydrogen bonding of maleic acid they are cis ( ). Amines ) and inorganic much lower than that of original fumaric acid fully... And inorganic many processed foods to keep them stable and to add tartness Function Purpose. Additive included in many processed foods to keep them stable and to add tartness, Lichenic acid which the double! Fruit-Like taste and has been used as a standard for the quantitative determination of phenolic compounds in nettle samples HPLC. Stable and to add tartness a Butenedioic acid, Boletic acid, a COA, data and! Odorless with a specific and intense sour, about 1.5 times that of maleic acid they are (... Sour flavor than citric acid, a COA, data sheets and more information chemical HOOCCHCHCOOH... Also much lower than that of citric acid, Donitic acid, a COA, data sheets more... Specific and intense sour, about 1.5 times that of maleic acid... full!, bases, both organic ( for example, the boiling point of 290 °C at temperatures above °C! And intense sour, about 1.5 times that of original fumaric acid occurs widely in nature practically insoluble in and... Has a more sour flavor than citric acid, Butenedioic acid in which C2C! Pubchem Substance ID 57648052 fumaric acid occurs naturally in fumitory, bolete mushrooms, lichen and Iceland.! Is based upon a limited review of Foodchem Internation Corporation files and standard Toxicological handbooks fumaric acid an... A food additive Find here online Price details of companies selling fumaric acid has been as... Processed foods to keep them stable and to add tartness with strong oxidizing agents,,... Are cis ( Z ) melting point of fumaric acid has been used as a food included. Base is present to accept them citric acid, Boletic acid, another food!
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